润滑油添加剂对柴油机颗粒物微观物理特性的影响研究*

doi:10.19562/j.chinasae.qcgc.2020.11.013

汽车工程 ›› 2020, Vol. 42 ›› Issue (11): 1545-1551.doi: 10.19562/j.chinasae.qcgc.2020.11.013

润滑油添加剂对柴油机颗粒物微观物理特性的影响研究^*

许广举, 高鉴, 李铭迪, 赵洋, 林玲

常熟理工学院汽车工程学院,常熟 215500

收稿日期:2019-11-04 出版日期:2020-11-25 发布日期:2021-01-25
通讯作者: 李铭迪,副教授,博士,E-mail:lmd-fj@163.com。
基金资助:
*国家自然科学青年基金项目(51506011)和江苏省自然科学青年基金项目(BK20160406)资助。

Study on the Effect of Lubricating Oil Additives on the Microphysical Properties of Diesel Particulate Matter

Xu Guangju, Gao Jian, Li Mingdi, Zhao Yang, Lin Ling

Department of Automobile Engineering, Changshu Institute of Technology, Changshu 215500

Received:2019-11-04 Online:2020-11-25 Published:2021-01-25

摘要/Abstract

摘要： 本文选用3种不同的润滑油添加剂配置了试验燃油,开展了柴油机台架试验并采集了颗粒物样品,综合运用SEM/TEM/Raman spectra等分析手段,研究了润滑油添加剂对颗粒物形貌特征、结构特征和石墨化程度的影响规律。研究结果表明,颗粒物直径取决于燃料多环芳香烃的含量。颗粒物的微晶尺寸随着燃料十六烷值的增加而减小,微晶尺寸越大,碳层结构的有序化程度越高。颗粒物基本碳粒子的曲率越大,碳层的电子共振稳定性越差。

关键词: 润滑油添加剂, 颗粒微观形态, 结构特征, 石墨化, 拉曼光谱

Abstract: In this paper, three different lubricating oil additives are used to configure the test fuel. The diesel engine bench tests are conducted and particulate samples are collected. Then the effect of lubricant additives on particle morphology, structural characteristics and graphitization degree are studied by means of SEM/TEM/Raman spectra. The results show that the particle diameter depends on the PAHs content of the fuel. The microcrystalline size of particles decreases with the increase of fuel cetane value. The larger the microcrystalline size, the higher the degree of ordering of carbon layer structure.The larger the curvature of the basic carbon particle, the worse the electron resonance stability of the carbon layer

Key words: lubricating oil additive, micromorphology of particles, structural characteristics, graphitization degree, Raman spectroscopy

许广举, 高鉴, 李铭迪, 赵洋, 林玲. 润滑油添加剂对柴油机颗粒物微观物理特性的影响研究^*[J]. 汽车工程, 2020, 42(11): 1545-1551.

Xu Guangju, Gao Jian, Li Mingdi, Zhao Yang, Lin Ling. Study on the Effect of Lubricating Oil Additives on the Microphysical Properties of Diesel Particulate Matter[J]. Automotive Engineering, 2020, 42(11): 1545-1551.

参考文献

[1] 褚国良,王国仰,祁金柱,等.CDPF被动再生特性及再生平衡条件研究[J].汽车工程,2019,41(12):1365-1369.
CHU Guoliang, WANG Guoyang, QI Jinzhu,et al. Study on passive regeneration characteristics and regeneration balance condition of CDPF[J]. Automotive Engineering,2019,41(12):1365-1369.
[2] 刘双喜, 邵忠英, 包俊江, 等. 燃油硫含量对国Ⅳ柴油轿车颗粒物排放特性的影响[J].汽车工程, 2011, 33(3):194-197.
LIU Shuangxi, SHAO Zhongying, BAO Junjiang,et al. The effects of fuel sulfur content on the characteristics of particulate emission in state-Ⅳ diesel cars[J]. Automotive Engineering,2011,33(3):194-197.
[3] KLEEMAN M J, RIDDLE S G, ROBERT M A, et al. Lubricating oil and fuel contributions to particulate matter emissions from light-duty gasoline and heavy-duty diesel vehicles.[J]. Environmental Science & Technology, 2008, 42(1):235-242.
[4] SINGH A K . Castor oil-based lubricant reduces smoke emission in two-stroke engines[J]. Industrial Crops & Products, 2011, 33(2):287-295.
[5] SONNTAG D B, BAILEY C R, FULPER C R, et al. Contribution of lubricating oil to particulate matter emissions from light-duty gasoline vehicles in Kansas city[J]. Environmental Science & Technology, 2012, 46(7):4191-4199.
[6] GOPAL K N, RAJ R T K. Effect of pongamia oil methyl ester-diesel blend on lubricating oil degradation of di compression ignition engine[J]. Fuel, 2016, 165:105-114.
[7] PIRJOLA L, KARJALAINEN P, HEIKKILÄ J, et al. Effects of fresh lubricant oils on particle emissions emitted by a modern gasoline direct injection passenger car[J]. Environmental Science & Technology, 2015, 49(6):3644-52.
[8] 王月森, 梁兴雨, 舒歌群, 等. 润滑油基础油对柴油机性能及排放的影响[J]. 内燃机学报, 2016,34(2):163-169.
WANG Yuesen, LIANG Xingyu, SHU Gequn, et al. Impact of lubricating base oil on diesel engine performance and emissions [J]. Transactions of CSICE ,2016,34(2):163-169.
[9] PENG X, GAO J, SHI G, et al. A preliminary assessment of the impacts of multiple temporal-scale variations in particulate matter on its source apportionment[J]. Atmospheric Chemistry & Physics, 2018:1-40.
[10] 崔应欣, 蔡忆昔, 施蕴曦, 等. 残余灰分对低温等离子体再生颗粒物捕集器的影响[J]. 西安交通大学学报, 2018, 52(11):154-159.
CUI Yingxin, CAI Yixi, SHI Yunxi, et al. Effects of residual ash on diesel particulate filter regeneration by non-thermal plasma technology[J]. Journal of Xi’an Jiaotong University ,2018,52(11):154-159.
[11] 方嘉, 蒋渊, 孟忠伟, 等. O₂/NO₂氛围下颗粒物的氧化催化特性试验[J]. 江苏大学学报(自然科学版), 2019,40(5):518-523.
FANG Jia, JIANG Yuan, MENG Zhongwei, et al. Oxidation and catalytic characteristics of particulate with O₂ /NO₂ condition[J]. Journal of Jiangsu University(Natural Science Edition) ,2019,40(5):518-523.
[12] BOTT R C, KIRK K M, LOGAN M B, et al. Diesel particulate matter and polycyclic aromatic hydrocarbons in fire stations[J]. Environ Sci Process Impacts, 2017, 19(10):1320-1326.
[13] LLAMAS A, AL-LAL A M, GARCÍA-MARTÍNEZ M J, et al. Polycyclic Aromatic Hydrocarbons (PAHs) produced in the combustion of fatty acid alkyl esters from different feedstocks: quantification, statistical analysis and mechanisms of formation[J]. Science of the Total Environment, 2017, 586:446-456.
[14] ZHANG C, WANG T, DING Y. Influence of Pt particle size on the activity of Pt/AC catalyst in selective oxidation of glycerol to Llactic acid[J]. Catalysis Letters, 2017, 147(5):1-7.
[15] 马志豪, 钞莹, 李磊,等. 柴油机后处理装置的颗粒排放物拉曼光谱研究[J]. 农业机械学报, 2013, 44(11):26-30.
MA Zhihao, CHAO Ying, LI Lei, et al. Raman spectroscopy research of particulate emissions from diesel engine with after-treatment device[J]. Transactions of the Chinese Society for Agricultural Machinery,2013, 44(11):26-30.
[16] 孟忠伟, 李鉴松, 秦源,等. DPF再生及其颗粒物数量浓度排放性能的试验[J]. 内燃机学报, 2019,37(4):329-336.
MENG Zhongwei, LI Jiansong, QIN Yuan, et al. Experimental on DPF regeneration and outlet particle concentration emission [J]. Transactions of CSICE ,2019,37(4):329-336.
[17] 赵洋, 许广举, 李铭迪,等. 柴油机EGR氛围下颗粒微观形貌与结构刚性的分析[J].汽车工程2016,38(9):1052-1057.
ZHAO Yang, XU Guangju, LI Mingdi, et al. An analysis on the micro-morphology and structure rigidity of particulates emitted from a diesel engine with EGR[J]. Automotive Engineering,2016,38(9):1052-1057.
[18] 赵洋, 王忠, 许广举, 等. 废气再循环对柴油机排气颗粒挥发与氧化特性的影响[J].汽车工程, 2016,38(8):935-940.
ZHAO Yang, WANG Zhong, XU Guangju, et al. The effects of exhaust gas recirculation on the volatilization and oxidation characteristics of particles from diesel engine [J]. Automotive Engineering,2016,38(8):935-940.
[19] 李铭迪, 王忠, 许广举,等. 柴油机燃用添加DTBP的生物柴油时排放颗粒粒径分布的研究[J]. 汽车工程, 2015,37(3):271-275.
LI Mingdi, WANG Zhong, XU Guangju, et al. A study on the size distribution of particulate emitted from diesel engine fueled with biodiesel adding DTBP [J]. Automotive Engineering,2015,37(3):271-275.

润滑油添加剂对柴油机颗粒物微观物理特性的影响研究^*

Study on the Effect of Lubricating Oil Additives on the Microphysical Properties of Diesel Particulate Matter

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 0

Metrics

本文评价

推荐阅读 10