The magnetic coupling mechanism, as the key component in the wireless charging system for electric vehicles, greatly determines the overall performance of the system. In this paper, a double D double Quadrature (DDDQ) magnetic coupled structure is proposed, which can not only improve the anti-offset capability of wireless charging system through coupling and complementing of the coils, but also be compatible with static wireless charging scenarios and dynamic wireless charging scenarios. To verify the performance of the proposed coupling structure, in this paper firstly simulation models for both static and dynamic wireless charging systems are established for testing and analysis. The simulation results show that the DDDQ magnetic coupling structure enhances coupling capability under offset conditions in static wireless charging and reduces coupling fluctuations in dynamic wireless charging. Secondly, the LCC-S compensation topology is chosen to compensate the power of system, and the output characteristics of static wireless charging system with different magnetic coupled structures are built and compared respectively, it is shown that wireless charging system based on the DDDQ magnetic coupled structure can still maintain better transmission capability in the case of misalignment. Then, the DDDQ magnetic coupled structure is applied to dynamic wireless charging scenario, and efficient resonant transmission is realized after configuring parameters. Finally, multiple test simulation points inside and outside the vehicle are selected according to relevant standards to evaluate the electromagnetic safety of the system in different scenarios. The results show that the DDDQ magnetic coupling structure meets electromagnetic safety standards.